Free 30-day trials of most Adobe software, including Photoshop, Dreamweaver, and Illustrator. Great to try a piece of software before commiting to buying it, and great if you're working on a project and don't need more than 30 days to complete it.
Adobe support forums for Dreamweaver. Great place to ask questions and learn more about the software.
The online Dreamweaver help from Adobe.
Free Dreamweaver tutorials from the excellent and highly-recommended Layers Magazine. Some are meant to be read, others are videos meant to be watched.
Google Sites is a free service that allows you to easily create websites and gives you a place to put them online. Since it is web-based, it works on any computer platform, and it does not require you to purchase or download any software. Consider this as an alternative to Dreamweaver or iWeb.
Safari Tech Books Online (PennKey required for access) offers several books on web design topics such as HTML, CSS, Javascript, as well as at least one Dreamweaver-specific book, "Dreamweaver CS3 The Missing Manual"

